/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

1 article(s) from Lange, Dominik A

Electronic differentiation competes with transition state sensitivity in palladium- catalyzed allylic substitutions

Dominik A. Lange and
Bernd Goldfuss

Beilstein J. Org. Chem. 2007, 3, No. 36, doi:10.1186/1860-5397-3-36

PDF

Graphical Abstract

Scheme 1: Electronic and steric differentiations provide the basis for the high selectivity of P,N-ligands in...

Jump to Scheme 1

Scheme 2: Activation (ΔE_a) and reaction (ΔE_r) energies (kcal mol^-1), computed for the P,N-ligand model with t...

Jump to Scheme 2

Figure 1: Transition structure for the energetically favored trans to phosphorus addition of ammonia at the P...

Jump to Figure 1

Figure 2: Transition structure for the energetically disfavored cis to phosphorus addition of ammonia at the ...

Jump to Figure 2

Figure 3: Transition structure for the energetically disfavored trans to phosphorus addition of ammonia at th...

Jump to Figure 3

Figure 4: Transition structure for the energetically favored cis to phosphorus addition of ammonia at the Pd-η...

Jump to Figure 4

Figure 5: Transition structure for the energetically favored trans to phosphorus addition of ammonia at the P...

Jump to Figure 5

Figure 6: Transition structure for the energetically disfavored cis to phosphorus addition of ammonia at the ...

Jump to Figure 6

Figure 7: Transition structure for the energetically disfavored cis to phosphorus addition of ammonia at the ...

Jump to Figure 7

Figure 8: Transition structure for the energetically favored trans to phosphorus addition of ammonia at the P...

Jump to Figure 8

Figure 9: For each phosphabenzene moiety, the site selectivities ΔE_a^TS increase with more electron withdrawin...

Jump to Figure 9

Figure 10: Higher site selectivities, i.e. larger ΔE_a^TS values, are found for earlier transition structures wi...

Jump to Figure 10

Figure 11: Higher site selectivities, i.e. larger ΔE_a^TS values, are found for transition structures with close...

Jump to Figure 11

Album

Full Research Paper

Published 26 Oct 2007

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum